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Concise and Enantioselective Total Synthesis of (−)-Mehranine, (−)-Methylenebismehranine, and Related Aspidosperma Alkaloids()
We report an efficient and highly stereoselective synthetic strategy for the synthesis of aspidosperma alkaloids based on the transannular cyclization of a chiral lactam precursor. Three new stereocenters are formed in this key step with excellent level of diastereoselection due to the conformationa...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4240000/ https://ncbi.nlm.nih.gov/pubmed/25196158 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201405609 |
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