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Evaluating the Uncertainty in Exchange Parameters Determined from Off-Resonance R1ρ Relaxation Dispersion for Systems in Fast Exchange
Spin relaxation in the rotating frame (R1ρ) is a powerful NMR technique for characterizing fast microsecond timescale exchange processes directed toward short-lived excited states in biomolecules. At the limit of fast exchange, only k(ex) = k(1) + k(−1) and Φ(ıx) = p(G)p(E)(Δω)(2) can be determined...
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| Veröffentlicht in: | J Magn Reson |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4222517/ https://ncbi.nlm.nih.gov/pubmed/24819426 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2014.04.010 |
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