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Evaluating the Uncertainty in Exchange Parameters Determined from Off-Resonance R1ρ Relaxation Dispersion for Systems in Fast Exchange

Spin relaxation in the rotating frame (R1ρ) is a powerful NMR technique for characterizing fast microsecond timescale exchange processes directed toward short-lived excited states in biomolecules. At the limit of fast exchange, only k(ex) = k(1) + k(−1) and Φ(ıx) = p(G)p(E)(Δω)(2) can be determined...

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發表在:J Magn Reson
Main Authors: Bothe, Jameson R., Stein, Zachary W., Al-Hashimi, Hashim M.
格式: Artigo
語言:Inglês
出版: 2014
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4222517/
https://ncbi.nlm.nih.gov/pubmed/24819426
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2014.04.010
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