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Nucleophilic Carbene Catalyzed Synthesis of 1,2 Amino Alcohols Via Azidation of Epoxy Aldehydes
[Image: see text] We report herein a nucleophilic carbene catalyzed redox azidation of epoxyaldehydes. The intermediate β-hydroxy acyl azides undergo thermal Curtius rearrangement followed by trapping with excess azide to form carbamoyl azides or, in a complementary sequence, by the hydroxy group to...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4222516/ https://ncbi.nlm.nih.gov/pubmed/18989930 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo8020055 |
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