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Intramolecular Polar [4(⊕) + 2]-Cycloadditions of Aryl-1-aza-2-azoniaallene Salts: Unprecedented Reactivity Leading to Polycyclic Protonated Azomethine Imines
[Image: see text] The first example of aryl-1-aza-2-azoniaallene salts undergoing a [4(⊕) + 2]-cycloaddition reaction in which the azo bond and one aromatic π-bond make up the 4π component is described. This intramolecular reaction appears to be concerted and provides high yields of protonated azome...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4219620/ https://ncbi.nlm.nih.gov/pubmed/24218159 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201306553 |
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