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Rhodium(III)-Catalyzed C–H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes
We have developed a synthesis of 4-substituted isoquinolones from the Rh(III)-catalyzed, C–H activation mediated, coupling of O-pivaloyl benzhydroxamic acids and 3,3-disubstituted cyclopropenes. Experiments suggest the formation of a [4.1.0] bicyclic-system, which can open under acidic conditions to...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4206942/ https://ncbi.nlm.nih.gov/pubmed/25346576 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0033-1339510 |
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