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Iron(II)-Catalyzed Intermolecular Amino-Oxygenation of Olefins through the N–O Bond Cleavage of Functionalized Hydroxylamines

[Image: see text] An iron-catalyzed diastereoselective intermolecular olefin amino-oxygenation reaction is reported, which proceeds via an iron-nitrenoid generated by the N–O bond cleavage of a functionalized hydroxylamine. In this reaction, a bench-stable hydroxylamine derivative is used as the ami...

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Autori principali: Lu, Deng-Fu, Zhu, Cheng-Liang, Jia, Zhen-Xin, Xu, Hao
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2014
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4183608/
https://ncbi.nlm.nih.gov/pubmed/25166591
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508057u
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