A New Tool To Guide Halofunctionalization Reactions: The Halenium Affinity (HalA) Scale

[Image: see text] We introduce a previously unexplored parameter—halenium affinity (HalA)– as a quantitative descriptor of the bond strengths of various functional groups to halenium ions. The HalA scale ranks potential halenium ion acceptors based on their ability to stabilize a “free halenium ion”...

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Main Authors: Ashtekar, Kumar Dilip, Marzijarani, Nastaran Salehi, Jaganathan, Arvind, Holmes, Daniel, Jackson, James E., Borhan, Babak
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2014
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4183602/
https://ncbi.nlm.nih.gov/pubmed/25152188
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506889c
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