Significant discrepancies between van't Hoff and calorimetric enthalpies.
In this paper we show that the usual assumption in studies of the temperature variation of equilibrium constants for equilibria of the form A+B <-->AB that a plot of ln K vs. 1/T (K = equilibrium constant, T = temperature in degrees kelvin) is a straight line with slope equal to -delta HvH/R (delta...
Shranjeno v:
| izdano v: | Proc Natl Acad Sci U S A |
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| Principais autores: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
National Academy of Sciences
1995
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC41743/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/7777555/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.92.12.5597 |
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