Significant discrepancies between van't Hoff and calorimetric enthalpies.
In this paper we show that the usual assumption in studies of the temperature variation of equilibrium constants for equilibria of the form A+B <-->AB that a plot of ln K vs. 1/T (K = equilibrium constant, T = temperature in degrees kelvin) is a straight line with slope equal to -delta HvH/R (delta...
Gespeichert in:
| Veröffentlicht in: | Proc Natl Acad Sci U S A |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
National Academy of Sciences
1995
|
| Schlagworte: | |
| Online-Zugang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC41743/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/7777555/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.92.12.5597 |
| Tags: |
Keine Tags, Fügen Sie das erste Tag hinzu!
|