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Synthesis of 2-substituted tryptophans via a C3- to C2-alkyl migration

The reaction of 3-substituted indoles with dehydroalanine (Dha) derivatives under Lewis acid-mediated conditions has been investigated. The formation of 2-substituted tryptophans is proposed to occur through a selective alkylative dearomatization–cyclization followed by C3- to C2-alkyl migration and...

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Bibliografiset tiedot
Päätekijät: Mari, Michele, Lucarini, Simone, Bartoccini, Francesca, Piersanti, Giovanni, Spadoni, Gilberto
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: Beilstein-Institut 2014
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4168769/
https://ncbi.nlm.nih.gov/pubmed/25246958
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.207
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