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Building complex carbon skeletons with ethynyl[2.2]paracyclophanes
Ethynyl[2.2]paracyclophanes are shown to be useful substrates for the preparation of complex, highly unsaturated carbon frameworks. Thus both the pseudo-geminal- 2 and the pseudo-ortho-diethynylcyclophane 4 can be dimerized by Glaser coupling to the respective dimers 9/10 and 11/12. Whereas the form...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4168697/ https://ncbi.nlm.nih.gov/pubmed/25246960 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.209 |
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