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Building complex carbon skeletons with ethynyl[2.2]paracyclophanes

Ethynyl[2.2]paracyclophanes are shown to be useful substrates for the preparation of complex, highly unsaturated carbon frameworks. Thus both the pseudo-geminal- 2 and the pseudo-ortho-diethynylcyclophane 4 can be dimerized by Glaser coupling to the respective dimers 9/10 and 11/12. Whereas the form...

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Autors principals: Dix, Ina, Bondarenko, Lidija, Jones, Peter G, Oeser, Thomas, Hopf, Henning
Format: Artigo
Idioma:Inglês
Publicat: Beilstein-Institut 2014
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4168697/
https://ncbi.nlm.nih.gov/pubmed/25246960
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.209
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