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The Influence of Oxygen on [NiFe]–Hydrogenase Cofactor Biosynthesis and How Ligation of Carbon Monoxide Precedes Cyanation
The class of [NiFe]–hydrogenases is characterized by a bimetallic cofactor comprising low–spin nickel and iron ions, the latter of which is modified with a single carbon monoxide (CO) and two cyanide (CN(−)) molecules. Generation of these ligands in vivo requires a complex maturation apparatus in wh...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Public Library of Science
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4161419/ https://ncbi.nlm.nih.gov/pubmed/25211029 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1371/journal.pone.0107488 |
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