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Nickel-Catalyzed Mizoroki–Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products()

Achieving high selectivity in the Heck reaction of electronically unbiased alkenes has been a longstanding challenge. Using a nickel-catalyzed cationic Heck reaction, we were able to achieve excellent selectivity for branched products (≥19:1 in all cases) over a wide range of aryl electrophiles and...

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Détails bibliographiques
Auteurs principaux: Tasker, Sarah Z., Gutierrez, Alicia C., Jamison, Timothy F.
Format: Artigo
Langue:Inglês
Publié: 2014
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4159703/
https://ncbi.nlm.nih.gov/pubmed/24402966
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201308391
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