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P450-catalyzed asymmetric cyclopropanation of electron-deficient olefins under aerobic conditions
A variant of P450 from Bacillus megaterium five mutations away from wild type is a highly active catalyst for cyclopropanation of a variety of acrylamide and acrylate olefins with ethyl diazoacetate (EDA). The very high rate of reaction enabled by histidine ligation allowed the reaction to be conduc...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4159215/ https://ncbi.nlm.nih.gov/pubmed/25221671 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C4CY00633J |
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