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EPR, ENDOR, and Electronic Structure Studies of the Jahn–Teller Distortion in an Fe(V) Nitride

[Image: see text] The recently synthesized and isolated low-coordinate Fe(V) nitride complex has numerous implications as a model for high-oxidation states in biological and industrial systems. The trigonal [PhB((t)BuIm)(3)Fe(V)≡N](+) (where (PhB((t)BuIm)(3)(–) = phenyltris(3-tert-butylimidazol-2-yl...

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Detalhes bibliográficos
Main Authors: Cutsail III, George E., Stein, Benjamin W., Subedi, Deepak, Smith, Jeremy M., Kirk, Martin L., Hoffman, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4156863/
https://ncbi.nlm.nih.gov/pubmed/25137531
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja505403j
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