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Triphosgene–Amine Base Promoted Chlorination of Unactivated Aliphatic Alcohols
Unactivated α-branched primary and secondary aliphatic alcohols have been successfully transformed into their corresponding alkyl chlorides in high yields upon treatment with a mixture of triphosgene and pyridine in dichloromethane at reflux. These mild chlorination conditions are high yielding, ste...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4153350/ https://ncbi.nlm.nih.gov/pubmed/23496045 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400341n |
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