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Highly Stereoselective Synthesis of Cyclopentanes bearing Four Stereocenters by a Rhodium Carbene–Initiated Domino Sequence

Stereoselective synthesis of a cyclopentane nucleus by convergent annulations constitutes a significant challenge for synthetic chemists. Though a number of biologically relevant cyclopentane natural products are known, more often than not, the cyclopentane core is assembled in a stepwise fashion du...

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Detalhes bibliográficos
Main Authors: Parr, Brendan T., Davies, Huw M. L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4149473/
https://ncbi.nlm.nih.gov/pubmed/25082301
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms5455
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