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Aerobic Damage to [FeFe]-Hydrogenases: Activation Barriers for the Chemical Attachment of O(2)**
[FeFe]-hydrogenases are the best natural hydrogen-producing enzymes but their biotechnological exploitation is hampered by their extreme oxygen sensitivity. The free energy profile for the chemical attachment of O(2) to the enzyme active site was investigated by using a range-separated density funct...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
WILEY-VCH Verlag
2014
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4143129/ https://ncbi.nlm.nih.gov/pubmed/24615978 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201400534 |
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