Wird geladen...

A Cooperative N-Heterocyclic Carbene-Chiral Phosphate Catalysis System for Allenolate Annulations

[Image: see text] The first highly enantioselective NHC-catalyzed [3+2] annulation reaction with α,β-alkynals and α-ketoesters has been developed. A new mode of cooperative catalysis involving the combination of a chiral Brønsted acid and a C(1)-symmetric biaryl saturated imidazolium precatalyst was...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Lee, Anna, Scheidt, Karl A.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2014
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4142640/
https://ncbi.nlm.nih.gov/pubmed/24895280
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201403446
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!