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Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms

[Image: see text] Though numerous catalysts for the dehydrogenation of ammonia borane (AB) are known, those that release >2 equiv of H(2) are uncommon. Herein, we report the synthesis of Mo complexes supported by a para-terphenyl diphosphine ligand, 1, displaying metal–arene interactions. Both a...

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Detalhes bibliográficos
Main Authors: Buss, Joshua A., Edouard, Guy A., Cheng, Christine, Shi, Jade, Agapie, Theodor
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4140452/
https://ncbi.nlm.nih.gov/pubmed/25034459
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5059923
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