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Mechanistic analysis of the ent-copalyl diphosphate synthases required for plant gibberellin hormone biosynthesis leads to novel product chemistry()

[Image: see text] An active site water molecule coordinated by conserved histidine and asparagine residues seems to serve as the catalytic base in all ent-copalyl diphosphate synthases (CPSs). When these residues are substituted by alanine, the mutant CPSs produce stereochemically novel ent-8-hydrox...

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Bibliografische gegevens
Hoofdauteurs: Potter, Kevin, Criswell, Jared, Zi, Jiachen, Stubbs, Alisha, Peters, Reuben J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2014
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4113509/
https://ncbi.nlm.nih.gov/pubmed/24862907
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201402911
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