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Qualitative Analysis of the Helical Electronic Energy of Inherently Chiral Calix[4]arenes: An Approach to Effectively Assign Their Absolute Configuration

For all microhelices on aromatic rings of inherently chiral calix[4]arene, an expression was derived from one approximation and one hypothesis on the basis of the electron-on-a-helix model of Tinoco and Woody as follows: [Image: see text] , where µ = 1 for the right-handed microhelix and µ = −1 for...

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Detalhes bibliográficos
Main Authors: Zheng, Shuang, Chang, Ming-Liang, Zhou, Jing, Fu, Jing-Wei, Zhang, Qing-Wei, Li, Shao-Yong, Qiao, Wei, Liu, Jun-Min
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4100125/
https://ncbi.nlm.nih.gov/pubmed/24897021
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms15069844
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