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Spectral evolution of a photochemical protecting group for orthogonal two-color uncaging with visible light
Caged compounds are molecules rendered functionally inert by derivatization with a photochemical protecting group. We describe the design logic behind the development of a diethylaminocoumarin (DEAC) caging chromophore, DEAC450, that absorbs blue light strongly (ε(450) = 43,000 M(-1) cm(-1)), and vi...
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| Main Authors: | , , , |
|---|---|
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2013
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4097017/ https://ncbi.nlm.nih.gov/pubmed/24117060 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja408225k |
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