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Spectral evolution of a photochemical protecting group for orthogonal two-color uncaging with visible light

Caged compounds are molecules rendered functionally inert by derivatization with a photochemical protecting group. We describe the design logic behind the development of a diethylaminocoumarin (DEAC) caging chromophore, DEAC450, that absorbs blue light strongly (ε(450) = 43,000 M(-1) cm(-1)), and vi...

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Autori principali: Olson, Jeremy P., Banghart, Matthew R., Sabatini, Bernardo L, Ellis-Davies, Graham C.R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4097017/
https://ncbi.nlm.nih.gov/pubmed/24117060
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja408225k
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