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n→π* Interactions Engender Chirality in Carbonyl Groups

[Image: see text] An n→π* interaction stems from the delocalization of the electron pair (n) of a donor group into the antibonding orbital (π*) of a carbonyl group. Crystallographic analyses of five pairs of diastereoisomers demonstrate that an n→π* interaction can induce chirality in an otherwise p...

詳細記述

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書誌詳細
主要な著者: Choudhary, Amit, Newberry, Robert W., Raines, Ronald T.
フォーマット: Artigo
言語:Inglês
出版事項: American Chemical Society 2014
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4096190/
https://ncbi.nlm.nih.gov/pubmed/24926562
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5012967
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