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Multiscale Reactive Molecular Dynamics for Absolute pK(a) Predictions and Amino Acid Deprotonation

[Image: see text] Accurately calculating a weak acid’s pK(a) from simulations remains a challenging task. We report a multiscale theoretical approach to calculate the free energy profile for acid ionization, resulting in accurate absolute pK(a) values in addition to insights into the underlying mech...

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Detalhes bibliográficos
Main Authors: Nelson, J. Gard, Peng, Yuxing, Silverstein, Daniel W., Swanson, Jessica M. J.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4095931/
https://ncbi.nlm.nih.gov/pubmed/25061442
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ct500250f
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