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Kβ Mainline X-ray Emission Spectroscopy as an Experimental Probe of Metal–Ligand Covalency

[Image: see text] The mainline feature in metal Kβ X-ray emission spectroscopy (XES) has long been recognized as an experimental marker for the spin state of the metal center. However, even within a series of metal compounds with the same nominal oxidation and spin state, significant changes are obs...

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Autori principali: Pollock, Christopher J., Delgado-Jaime, Mario Ulises, Atanasov, Mihail, Neese, Frank, DeBeer, Serena
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2014
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4091279/
https://ncbi.nlm.nih.gov/pubmed/24914450
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja504182n
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