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Demonstration of Heterogeneous Parahydrogen Induced Polarization Using Hyperpolarized Agent Migration from Dissolved Rh(I) Complex to Gas Phase

[Image: see text] Parahydrogen-induced polarization (PHIP) was used to demonstrate the concept that highly polarized, catalyst-free fluids can be obtained in a catalysis-free regime using a chemical reaction with molecular addition of parahydrogen to a water-soluble Rh(I) complex carrying a payload...

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Main Authors: Kovtunov, Kirill V., Barskiy, Danila A., Shchepin, Roman V., Coffey, Aaron M., Waddell, Kevin W., Koptyug, Igor V., Chekmenev, Eduard Y.
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2014
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4079322/
https://ncbi.nlm.nih.gov/pubmed/24918975
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ac5013859
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