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Parahydrogen Induced Polarization with Rh-based Monodentate Ligand in Water

Reported here is a water soluble Rh(I)-based catalyst for performing parahydrogen induced polarization (PHIP). The [Rh(I)(norbornadiene)(THP)(2)](+)[BF(4)](-) catalyst utilizes the monodentate phosphine ligand tris(hydroxymethyl)phosphine (THP). The monodentate PHIP catalyst is less susceptible to o...

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Bibliografische gegevens
Hoofdauteurs: Shchepin, Roman V., Coffey, Aaron M., Waddell, Kevin W., Chekmenev, Eduard Y.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2012
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3515067/
https://ncbi.nlm.nih.gov/pubmed/23227297
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz301389r
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