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Parahydrogen Induced Polarization with Rh-based Monodentate Ligand in Water
Reported here is a water soluble Rh(I)-based catalyst for performing parahydrogen induced polarization (PHIP). The [Rh(I)(norbornadiene)(THP)(2)](+)[BF(4)](-) catalyst utilizes the monodentate phosphine ligand tris(hydroxymethyl)phosphine (THP). The monodentate PHIP catalyst is less susceptible to o...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3515067/ https://ncbi.nlm.nih.gov/pubmed/23227297 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz301389r |
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