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Homogeneous and heterogeneous photoredox-catalyzed hydroxymethylation of ketones and keto esters: catalyst screening, chemoselectivity and dilution effects

The homogeneous titanium- and dye-catalyzed as well as the heterogeneous semiconductor particle-catalyzed photohydroxymethylation of ketones by methanol were investigated in order to evaluate the most active photocatalyst system. Dialkoxytitanium dichlorides are the most efficient species for chemos...

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Autors principals: Griesbeck, Axel G, Reckenthäler, Melissa
Format: Artigo
Idioma:Inglês
Publicat: Beilstein-Institut 2014
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4077468/
https://ncbi.nlm.nih.gov/pubmed/24991265
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.114
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