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Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis
The Co(II) complex of a new D(2)-symmetric chiral porphyrin 3,5-DiMes-QingPhyrin, [Co(P6)], can catalyze asymmetric aziridination of alkenes with bis(2,2,2-trichloroethyl)phosphoryl azide (TcepN(3)) as a nitrene source. This new Co(II)-based metalloradical aziridination is suitable for different aro...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Beilstein-Institut
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4077377/ https://ncbi.nlm.nih.gov/pubmed/24991280 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.129 |
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