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Hydrodynamic and Nonhydrodynamic Contributions to the Bimolecular Collision Rates of Solute Molecules in Supercooled Bulk Water

[Image: see text] Bimolecular collision rate constants of a model solute are measured in water at T = 259–303 K, a range encompassing both normal and supercooled water. A stable, spherical nitroxide spin probe, perdeuterated 2,2,6,6-tetramethyl-4-oxopiperidine-1-oxyl, is studied using electron param...

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Bibliografski detalji
Glavni autori: Peric, Ida, Merunka, Dalibor, Bales, Barney L., Peric, Miroslav
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2014
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4076007/
https://ncbi.nlm.nih.gov/pubmed/24874024
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp501330x
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