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Rotation of Four Small Nitroxide Probes in Supercooled Bulk Water
Using a precise method of least-squares nonlinear electron paramagnetic resonance (EPR) line fitting, we have obtained experimental evidence of a decoupling of the rotational motion of four nitroxide spin probes from the viscosity of bulk water at 277 K. This decoupling is about 50 K higher than ano...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3593304/ https://ncbi.nlm.nih.gov/pubmed/23493516 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz302107x |
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