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Rotation of Four Small Nitroxide Probes in Supercooled Bulk Water

Using a precise method of least-squares nonlinear electron paramagnetic resonance (EPR) line fitting, we have obtained experimental evidence of a decoupling of the rotational motion of four nitroxide spin probes from the viscosity of bulk water at 277 K. This decoupling is about 50 K higher than ano...

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Bibliographic Details
Main Authors: Peric, Ida, Merunka, Dalibor, Bales, Barney L., Peric, Miroslav
Format: Artigo
Language:Inglês
Published: 2013
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3593304/
https://ncbi.nlm.nih.gov/pubmed/23493516
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz302107x
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