The First Example of Nickel-Catalyzed Silyl-Heck Reactions: Direct Activation of Silyl Triflates Without Iodide Additives

For the first time, nickel-catalyzed silyl-Heck reactions are reported. Using simple phosphine-supported nickel catalysts, direct activation of silyl triflates has been achieved. These results contrast earlier palladium-catalyzed systems, which require iodide additives to activate silyl-triflates. T...

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Main Authors: McAtee, Jesse R., Martin, Sara E. S., Cinderella, Andrew P., Reid, William B., Johnson, Keywan A., Watson, Donald A.
Format: Artigo
Sprog:Inglês
Udgivet: 2014
Fag:
Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4047519/
https://ncbi.nlm.nih.gov/pubmed/24914247
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2014.03.021
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