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Visible-Light Organic Photocatalysis for Latent Radical-Initiated Polymerization via 2e(–)/1H(+) Transfers: Initiation with Parallels to Photosynthesis

[Image: see text] We report the latent production of free radicals from energy stored in a redox potential through a 2e(–)/1H(+) transfer process, analogous to energy harvesting in photosynthesis, using visible-light organic photoredox catalysis (photocatalysis) of methylene blue chromophore with a...

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Detalhes bibliográficos
Main Authors: Aguirre-Soto, Alan, Lim, Chern-Hooi, Hwang, Albert T., Musgrave, Charles B., Stansbury, Jeffrey W.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4046762/
https://ncbi.nlm.nih.gov/pubmed/24786755
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja502441d
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