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An anionic N-donor ligand promotes manganese-catalyzed water oxidation

Four manganese complexes of pentadentate ligands have been studied for their ability to act as oxygen-evolution catalysts in the presence of Oxone or hydrogen peroxide. The complexes [Mn(PaPy(3))(NO(3))](ClO(4)), 1 (PaPy(3)H = N,N-bis(2-pyridylmethyl)-amine-N-ethyl-2-pyridine-2-carboxamide) and [Mn(...

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Detalhes bibliográficos
Main Authors: Young, Karin J., Takase, Michael K., Brudvig, Gary W.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4040523/
https://ncbi.nlm.nih.gov/pubmed/23777320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic400691e
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