Ionic asymmetry and solvent excluded volume effects on spherical electric double layers: A density functional approach

In this article, we present a classical density functional theory for electrical double layers of spherical macroions that extends the capabilities of conventional approaches by accounting for electrostatic ion correlations, size asymmetry, and excluded volume effects. The approach is based on a rec...

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Bibliografiske detaljer
Main Authors: Medasani, Bharat, Ovanesyan, Zaven, Thomas, Dennis G., Sushko, Maria L., Marucho, Marcelo
Format: Artigo
Sprog:Inglês
Udgivet: AIP Publishing LLC 2014
Fag:
Liquids, Glasses, and Crystals
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4039739/
https://ncbi.nlm.nih.gov/pubmed/24880304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4876002
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