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Ionic asymmetry and solvent excluded volume effects on spherical electric double layers: A density functional approach

In this article, we present a classical density functional theory for electrical double layers of spherical macroions that extends the capabilities of conventional approaches by accounting for electrostatic ion correlations, size asymmetry, and excluded volume effects. The approach is based on a rec...

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Detalhes bibliográficos
Main Authors: Medasani, Bharat, Ovanesyan, Zaven, Thomas, Dennis G., Sushko, Maria L., Marucho, Marcelo
Formato: Artigo
Idioma:Inglês
Publicado em: AIP Publishing LLC 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4039739/
https://ncbi.nlm.nih.gov/pubmed/24880304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4876002
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