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Predicting the influence of long-range molecular interactions on macroscopic-scale diffusion by homogenization of the Smoluchowski equation

The macroscopic diffusion constant for a charged diffuser is in part dependent on (1) the volume excluded by solute “obstacles” and (2) long-range interactions between those obstacles and the diffuser. Increasing excluded volume reduces transport of the diffuser, while long-range interactions can ei...

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Autori principali: Kekenes-Huskey, P. M., Gillette, A. K., McCammon, J. A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: AIP Publishing LLC 2014
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4032425/
https://ncbi.nlm.nih.gov/pubmed/24811624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4873382
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