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Copper(I)-Catalyzed Cycloaddition of Bismuth(III) Acetylides with Organic Azides: Synthesis of Stable Triazole Anion Equivalents

[Image: see text] Readily accessible and shelf-stable 1-bismuth(III) acetylides react rapidly and regiospecifically with organic azides in the presence of a copper(I) catalyst. The reaction tolerates many functional groups and gives excellent yields of the previously unreported, bench-stable 5-bismu...

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Autors principals: Worrell, Brady T., Ellery, Shelby P., Fokin, Valery V.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4010115/
https://ncbi.nlm.nih.gov/pubmed/24130150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201306192
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