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Conformational analysis of 2,2-difluoroethylamine hydrochloride: double gauche effect
The gauche effect in fluorinated alkylammonium salts is well known and attributed either to an intramolecular hydrogen bond or to an electrostatic attraction between the positively charged nitrogen and the vicinal electronegative fluorine atom. This work reports the effect of adding a fluorine atom...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3999868/ https://ncbi.nlm.nih.gov/pubmed/24778743 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.84 |
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