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Conformational analysis of 2,2-difluoroethylamine hydrochloride: double gauche effect

The gauche effect in fluorinated alkylammonium salts is well known and attributed either to an intramolecular hydrogen bond or to an electrostatic attraction between the positively charged nitrogen and the vicinal electronegative fluorine atom. This work reports the effect of adding a fluorine atom...

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Hlavní autoři: Silla, Josué M, Duarte, Claudimar J, Cormanich, Rodrigo A, Rittner, Roberto, Freitas, Matheus P
Médium: Artigo
Jazyk:Inglês
Vydáno: Beilstein-Institut 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3999868/
https://ncbi.nlm.nih.gov/pubmed/24778743
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.84
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