An Approach to Cyclohepta[b]indoles through an Allenamide (4 + 3) Cycloaddition–Grignard Cyclization–Chugaev Elimination Sequence

[Image: see text] A strategy for synthesizing highly functionalized cyclohepta[b]indoles through a concise (4 + 3) cycloaddition–cyclization–elimination sequence is described. The cycloaddition features nitrogen-stabilized oxyallyl cations derived from epoxidations of N-aryl-N-sulfonyl-substituted a...

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Main Authors: He, Shuzhong, Hsung, Richard P., Presser, William R., Ma, Zhi-Xiong, Haugen, Bryan J.
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2014
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3998770/
https://ncbi.nlm.nih.gov/pubmed/24701990
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5006455
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