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A Highly Stereoselective Diels-Alder Cycloaddition of Enones with Chiral Cyclic 2-Amidodienes Derived from Allenamides
[Image: see text] Lewis acid promoted Diels-Alder cycloadditions of a series of de novo chiral cyclic 2-amidodienes are described. These cyclic 2-amidodienes are derived from chiral α–allyl allenamides via a sequence of E-selective 1,3-H shift and 6π–electron pericyclic ring-closure. With enones ser...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3823681/ https://ncbi.nlm.nih.gov/pubmed/24001055 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol402254p |
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