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Stereoselective Synthesis of Isoquinuclidines through an Aza-[4 + 2] Cycloaddition of Chiral Cyclic 2-Amidodienes
[Image: see text] A highly stereoselective aza-[4 + 2] cycloaddition of chiral cyclic 2-amidodienes with N-sulfonyl aldimines is described. While this Lewis acid promoted heterocycloaddition provides an efficient strategy for constructing optically enriched isoquinuclidines, it is mechanistically in...
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| Main Authors: | , |
|---|---|
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
American Chemical
Society
2014
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| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3969095/ https://ncbi.nlm.nih.gov/pubmed/24621094 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol500390a |
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