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Conversion between Doubly and Triply Carboxylate Bridged Bis(ethylzinc) Complexes and Formation of the (μ-Oxo)tetrazinc Carboxylate [Zn(4)O(Ar(Tol)CO(2))(6)]
[Image: see text] Ethylzinc 2,6-bis(p-tolyl)benzoate converts between two forms in solution. Through NMR spectroscopic techniques and X-ray crystallography, the species in equilibrium were identified as [Zn(2)(Ar(Tol)CO(2))(2)(Et)(2)(THF)(2)] (1), [Zn(2)(Ar(Tol)CO(2))(3)(Et)(THF)] (2), and diethylzi...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3994167/ https://ncbi.nlm.nih.gov/pubmed/24761049 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5000503 |
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