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Intramolecular Nitrogen Delivery for the Synthesis of C-Glycosphingolipids. Application to the C-Glycoside of the Immunostimulant KRN7000

[Image: see text] The key reaction in this approach to C-glycosphingolipids is the stereoselective iodocyclization of a sugar-linked homoallylic carbonimidothioate. E and Z reaction substrates were assembled in a convergent fashion via an alkene metathesis strategy and exhibited the same alkene faci...

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Bibliografiska uppgifter
Huvudupphovsmän: Altiti, Ahmad S., Mootoo, David R.
Materialtyp: Artigo
Språk:Inglês
Publicerad: American Chemical Society 2014
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3993873/
https://ncbi.nlm.nih.gov/pubmed/24559301
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5002686
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