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Radical Reactivity of the Fe(III)/(II) Tetramesitylporphyrin Couple: Hydrogen Atom Transfer, Oxyl Radical Dissociation, and Catalytic Disproportionation of a Hydroxylamine
The chemistry of low-valent iron porphyrin complexes with oxyl radical reagents has been explored. (Meso-tetramesityl porphyrinato) iron(III) hydroxide, (TMP)Fe(III)(OH) reacts with the hydroxylamine TEMPO–H (1-hydroxy-2,2,6,6-tetramethylpiperdine) to yield the ferrous porphyrin, (TMP)Fe(II), togeth...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3981745/ https://ncbi.nlm.nih.gov/pubmed/24729854 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC52055B |
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