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Helically chiral polymers: A class of ligands for asymmetric catalysis
Helically chiral polymers from achiral monomers containing N and P atoms have been shown to be ligands for transition metals such as Pd and Rh. The Rh complex of the phosphane-containing polyisocyanate p(18-co-17) was an active albeit hardly enantioselective catalyst in the asymmetric hydrogenation...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
National Academy of Sciences
2004
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC397405/ https://ncbi.nlm.nih.gov/pubmed/15054138 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307443101 |
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